Crystal structure of 1,1,5,5-tetramethyl-1,2,5,6-tetrahydro-3a,4,7a,8-tetraaza- s-indacene-3,7-dione, C12H16N4O2

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2,6-Dibenzyl-1,2,3,5,6,7-hexahydro-2,4,6,8-tetraaza-s-indacene and 2,6-bis(4-methoxybenzyl)-1,2,3,5,6,7-hexahydro-2,4,6,8-tetraaza-s-indacene.

The title compounds, C22H22N4 and C24H26N4O2 [alternative names: 2,6-dibenzyl-2,3,6,7-tetrahydro-1H,5H-dipyrrolo[3,4-b; 3',4'-e]pyrazine and 2,6-bis(4-methoxybenzyl)-2,3,6,7-tetrahydro-1H,5H-dipyrolo[3,4-b;3',4'-e]pyrazine], two 1,2,3,5,6,7-hexahydro-2,4,6,8-tetraaza-s-indacene derivatives, are both centrosymmetric and have similar S-shaped structures. In the former, there are two independent m...

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Crystal structure of 1,3,4-triphenyl-pyrrole-2,5-dione.

withdrawing groups and an electron-donating group. The electron-withdrawing groups are further conjugated with a double bond in the ring. The light-absorption characteristics of the molecule are expected to be modified by changing the substituents attached to the molecule. This indicates that the molecule can be one of the basic components in designing functional dyes. It is therefore of partic...

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Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione

In the title compound, C9H15NO2, the piperidine ring exhibits a chair conformation. The butane-dione subunit exhibits a conformation with the ketone C atom in an eclipsed position with respect to the amide carbonyl group. In the crystal, a two-dimensional layered arrangement is formed by hydrogen bonds of the C-H⋯O type between the methyl group and the exocyclic methyl-ene unit as donor sites a...

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Crystal structure of (5′S,8′S)-3-(2,5-di­methyl­phen­yl)-8-meth­oxy-3-nitro-1-aza­spiro­[4.5]decane-2,4-dione

The title compound, C18H22N2O5, was synthesized by nitrification of its enol precursor. The pyrrolidine ring plane adopts a twisted conformation about the C-C bond linking the spiro centre and the C=O group remote from the N atom. It makes dihedral angles of 71.69 (9) and 88.92 (9)°, respectively, with the benzene ring plane and the plane defined by the four C atoms that form the seat of the of...

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Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ4 S,N 1,N 1′,S′](pyridine-κN)zinc(II)

In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the Zn(II) ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis-(thio-semicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N-H⋯N and N-H⋯S hydrogen-bonding interactions extend parallel to [10-1].

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ژورنال

عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures

سال: 2003

ISSN: 2197-4578,1433-7266

DOI: 10.1524/ncrs.2003.218.3.331